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Creators/Authors contains: "Castañeda, I"

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  1. Climate changes during the mid- to late-Holocene, after the last vestiges of glacial ice sheets dwindled, provide important context for climate change today. In the tropical Andes, most of the continuous paleoclimate records covering the late Holocene are derived from the oxygen isotope composition of ice cores, speleothems, and lake carbonates. These archives are powerful recorders of large-scale changes in circulation and monsoon intensity, but they do not necessarily capture local moisture balance, and so reconstructions of local precipitation and aridity remain scarce. Here we present contrasting histories of local effective moisture vs. regional circulation from several new biomarker records preserved in lakes and peat in the Colombian and Peruvian Andes. We focus on the hydrogen isotope composition of long-chain plant waxes, which reflects precipitation δ2H similarly to δ18O from ice cores and speleothems; and the δ13C of waxes and the δ2H of mid-chain waxes, which reflect local water stress and effective moisture. In both the Northern and Southern Hemisphere tropical Andes, fairly gradual δ2H shifts during the late Holocene indicate a progressive intensification of circulation in the South American lowlands. On the other hand, plant wax δ13C and mid-chain δ2H records indicate abrupt transitions into and out of intervals of water stress and aridity – similar to findings from pollen and sediment lithology from elsewhere in the tropical Andes. We draw on climate models and proxy data syntheses to help reconcile these curiously different accounts of effective moisture in the tropical Andes since the mid-Holocene and discuss implications for modern climate research. 
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    Free, publicly-accessible full text available December 10, 2025
  2. Abstract Quantitative temperature reconstructions from lacustrine organic geochemical proxies including branched glycerol dialkyl glycerol tetraethers (brGDGTs) and alkenones provide key constraints on past continental climates. However, estimation of air temperatures from proxies can be impacted by non‐stationarity in the relationships between seasonal air and water temperatures, a factor not yet examined in strongly seasonal high‐latitude settings. We pair downcore analyses of brGDGTs and alkenones measured on the same samples through the Holocene with forward‐modeled proxy values based on thermodynamic lake model simulations for a western Greenland lake. The measured brGDGT distributions suggest that stable autochthonous (aquatic) production overpowers allochthonous inputs for most samples, justifying the use of the lake model to interpret temperature‐driven changes. Conventional calibration of alkenones (detected only after 5.5 thousand years BP) suggests substantially larger temperature variations than conventional calibration of brGDGTs. Comparison of proxy measurements to forward‐modeled values suggests variations in brGDGT distributions monotonically reflect multi‐decadal summer air temperatures changes, although the length of the ice‐free season dampens the influence of air temperatures on water temperatures. Drivers of alkenone variability remain less clear; potential influences include small changes in the seasonality of proxy production or biases toward specific years, both underlain by non‐linearity in water‐air temperature sensitivity during relevant seasonal windows. We demonstrate that implied temperature variability can differ substantially between proxies because of differences in air‐water temperature sensitivity during windows of proxy synthesis without necessitating threshold behavior in the lake or local climate, and recommend that future studies incorporate lake modeling to constrain this uncertainty. 
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  3. Abstract Key features of late Neogene climate remain uncertain due to conflicting records derived from different sea surface temperature (SST) proxies. To understand scenarios in which proxy‐derived temperature estimates can be used interchangeably or are instead measuring different aspects of the same system, it is necessary to explore both the consistencies and differences between specific paleothermometers. Here, we report orbital‐scale climate records from ODP Site 846 in the eastern equatorial Pacific (EEP) for the interval from ~5–6 Ma using alkenone and archaeal lipid paleothermometers. Results from both proxies are similar in their secular trends and magnitude of long‐term temperature change, and spectral analysis demonstrates that the records are coherent and in‐phase in both the obliquity and precession bands. However, we find that the temperatures reconstructed by TEX86are consistently offset toward colder values by ~2 °C relative to Uk′37‐derived temperatures in global calibrations, or by ~0.8 °C in Bayesian‐based calibrations. All combinations of calibrations also yield approximately twice the amplitude of orbital‐scale variation in TEX86relative to Uk′37‐derived temperature fluctuations. Both temperature proxies are negatively correlated with sedimentary alkenone concentrations, which we use as an indicator of increased export productivity. Removing this productivity contribution from TEX86results in an adjusted TEX86record with temperature sensitivity identical to Uk′37. In future applications, this signal may be decoupled using additional sedimentary indicators of paleoproductivity, which likely will be most important for upwelling zone environments. There remain other nonexplained factors that contribute to differences between TEX86and Uk′37that warrant additional investigation. 
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